KATALIZA ASYMETRYCZNA
UMCS - Studia Doktoranckie
XI - XII. 2008
KATALIZA
ORGANOKATALIZA
KATALIZA ASYMETRYCZNA
UMCS - Studia Doktoranckie
XI - XII. 2008
KATALIZA
ORGANOKATALIZA
KATALIZA ASYMETRYCZNA
z udziałem metali przejściowych
The Nobel Prize in Chemistry
2001
"for their work on chirally catalysed hydrogenation reactions„
"for his work on chirally catalysed oxidationreactions"
William S. Knowles
Ryoji Noyori
K. Barry Sharpless
1/4 of the prize
1/4 of the prize
1/2 of the prize
USA
Japan
USA
St. Louis, MO, USA
Nagoya University
Nagoya, Japan
The Scripps Research Institute
La Jolla, CA, USA
b. 1917
b. 1938
b. 1941
Dr William S. Knowles
Prof. Ryoji Noyori
Prof. K. Barry Sharpless
Rh
Cl
PPh
3
PPh
3
Ph
3
P
Pd
o
PPh
3
PPh
3
Ph
3
P
PPh
3
Wilkinson
Malatesta
William S. Knowles
William S. Knowles
William S. Knowles
William S. Knowles
William S. Knowles
William S. Knowles
William S. Knowles
William S. Knowles
William S. Knowles
William S. Knowles
William S. Knowles
William S. Knowles
Qudrant rules
William S. Knowles
William S. Knowles
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
Ryoji Noyori
K. Barry Sharpless
Asymmetric epoxidation of allylic alcohols
K. Barry Sharpless
Asymmetric epoxidation of allylic alcohols
K. Barry Sharpless
Chirally predictive model
Asymmetric epoxidation of allylic alcohols
K. Barry Sharpless
Asymmetric dihydroxylation of olefins
AD
-mix
α
AD
-mix
β
K. Barry Sharpless
K. Barry Sharpless
Asymmetric dihydroxylation of squalene
K. Barry Sharpless
K. Barry Sharpless
K. Barry Sharpless