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pobrano z www.sqlmedia.pl
Chemia. Poziom rozszerzony
3UöEQD0DWXUD]23(521(0Lķ*D]HWÈ:\ERUF]Èĵ
16
BRUDNOPIS
QLHSRGOHJDRFHQLH
pobrano z www.sqlmedia.pl
Chemia
Poziom rozszerzony
KRYTERIA OCENIANIA ODPOWIEDZI
Próbna Matura z OPERONEM
Listopad 2013
:QLQLHMV]\PVFKHPDFLHRFHQLDQLD]DGDñRWZDUW\FKVÈSUH]HQWRZDQHSU]\NïDGRZHSRSUDZQHRGSRZLHG]L
:WHJRW\SX]DGDQLDFKQDOHĝ\UöZQLHĝX]QDÊRGSRZLHG]LXF]QLDMHĂOLVÈLQDF]HMVIRUPXïRZDQHDOHLFKVHQV
MHVW]JRGQ\]SRGDQ\PVFKHPDWHPRUD]LQQHSRSUDZQHRGSRZLHG]LZQLPQLHSU]HZLG]LDQH
w w w. o p e r o n . p l
1
Numer
zadania
3RSUDZQDRGSRZLHGěL]DVDG\SU]\]QDZDQLDSXQNWöZ
Liczba
SXQNWöZ
1.
3RSUDZQDRGSRZLHGě
6\PEROSLHUZLDVWND;&D
/LF]EDDWRPRZDSLHUZLDVWND;
1
1 pkt – poprawne podanie symbolu oraz liczby atomowej pierwiastka
SNWļQLHSRSUDZQDRGSRZLHGěOXEEUDNRGSRZLHG]L
3RSUDZQDRGSRZLHGě
1s
s
p
6
3s
3p
6
4s
1
SNWļSRSUDZQHSRGDQLHNRQğJXUDFMLHOHNWURQRZHM
SNWļQLHSRSUDZQHSRGDQLHNRQğJXUDFMLHOHNWURQRZHMOXEEUDNRGSRZLHG]L
3.
3RSUDZQDRGSRZLHGě
Liczba kwantowa
Elektron 1
(OHNWURQ
n
4
4
l
m
m
s
1
2
1
2
1
1 pkt – poprawne podanie stanu dwóch elektronów walencyjnych
SNWļSRSUDZQHSRGDQLHVWDQXMHGQHJRHOHNWURQXZDOHQF\MQHJRQLHSRSUDZQH
podanie stanu dwóch elektronów walencyjnych lub brak odpowiedzi
4.
3RSUDZQDRGSRZLHGě
1
1 pkt – poprawne podanie liczby atomowej pierwiastka
SNWļQLHSRSUDZQHSRGDQLHOLF]E\DWRPRZHMSLHUZLDVWNDOXEEUDNRGSRZLHG]L
pobrano z www.sqlmedia.pl
Chemia. Poziom rozszerzony
3UöEQD0DWXUD]23(521(0Lķ*D]HWÈ:\ERUF]Èĵ
w w w. o p e r o n . p l
2
Numer
zadania
3RSUDZQDRGSRZLHGěL]DVDG\SU]\]QDZDQLDSXQNWöZ
Liczba
SXQNWöZ
5.
3U]\NïDGSRSUDZQHMRGSRZLHG]L
&]DV>ODWD@
3R]RVWDïDPDVD>J@
ļĿ
ļĿ
ļĿ
ļĿ
2GSRZLHGě=SUöENLRPDVLHJWHJRL]RWRSXSR]RVWDQLHJSRODWDFK
SNWļ]DVWRVRZDQLHSRSUDZQHMPHWRG\REOLF]HñSRSUDZQHZ\NRQDQLHREOLF]Hñ
SRGDQLHSRSUDZQHJRZ\QLNXZUD]]MHGQRVWNÈ
SNWļ]DVWRVRZDQLHSRSUDZQHMPHWRG\REOLF]HñDOHSRSHïQLHQLHEïÚGöZUDFKXQ-
NRZ\FKSURZDG]ÈF\FKGREïÚGQHJRZ\QLNXOXESRGDQLHZ\QLNX]EïÚGQÈ
MHGQRVWNÈOXEEUDNZ\QLNX
SNWļ]DVWRVRZDQLHQLHSRSUDZQHMPHWRG\REOLF]HñOXEEUDNREOLF]Hñ
6.
3U]\NïDGSRSUDZQHMRGSRZLHG]L
v
v
k
k
k
2
1
2
2
3
2
2
3
2
2
3
1
2
N
3H
N
H
1
2
N
27 H
k
=
⋅
⋅
[
]
⋅
[ ]
⋅
[ ]
=
⋅ ⋅
[ ]
⋅
⋅
[ ]
⋅⋅
[ ]
⋅
[ ]
=
N
H
13,5
2
2
3
2GSRZLHGě6]\ENRĂÊUHDNFMLZ]URĂQLHUD]D
SNWļ]DVWRVRZDQLHSRSUDZQHMPHWRG\REOLF]HñSRSUDZQHZ\NRQDQLHREOLF]Hñ
RUD]SRGDQLHSRSUDZQHJRZ\QLNX
SNWļ]DVWRVRZDQLHSRSUDZQHMPHWRG\REOLF]HñLSRSHïQLHQLHEïÚGöZUDFKXQNR-
Z\FKSURZDG]ÈF\FKGREïÚGQHJRZ\QLNXOLF]ERZHJR
SNWļ]DVWRVRZDQLHQLHSRSUDZQHMPHWRG\REOLF]HñOXEEUDNRGSRZLHG]L
7.
3U]\NïDGSRSUDZQHMRGSRZLHG]L
=Q6+12
3
$=Q12
3
+
S
=Q12
3
1D2+$=Q2+
1D12
3
=Q2+
1D2+$1D
>=Q2+
4
@
3
SNWļSRSUDZQH]DSLVDQLHWU]HFKUöZQDñUHDNFML
SNWļSRSUDZQH]DSLVDQLHGZöFKUöZQDñUHDNFML
SNWļSRSUDZQH]DSLVDQLHMHGQHJRUöZQDQLDUHDNFML
SNWļEUDNSRSUDZQLH]DSLVDQ\FKUöZQDñUHDNFMLOXEEUDNRGSRZLHG]L
8.
3RSUDZQDRGSRZLHGě
3UREöZND,]DVDGRZ\
3UREöZND,,RERMÚWQ\
3UREöZND,,,NZDVRZ\
1
1 pkt – poprawne podanie odczynu w trzech probówkach
SNWļSRSUDZQHSRGDQLHRGF]\QXZGZöFKOXEZMHGQHMSUREöZFHEUDNSR-
SUDZQLHSRGDQHJRRGF]\QXOXEEUDNRGSRZLHG]L
9.
3RSUDZQDRGSRZLHGě
3UREöZND,&+
3
&22
–
+
O m&+
3
&22+2+
–
3UREöZND,,K\GUROL]DQLH]DFKRG]L
3UREöZND,,,1+
4
+
O m1+
3
+
3
O
1
SNWļSRSUDZQH]DSLVDQLHGZöFKUöZQDñUHDNFMLRUD]]D]QDF]HQLHĝHUHDNFMDQLH
zachodzi dla jednej probówki
SNWļEUDNSRSUDZQHMRGSRZLHG]LOXEEUDNRGSRZLHG]L
pobrano z www.sqlmedia.pl
Chemia. Poziom rozszerzony
3UöEQD0DWXUD]23(521(0Lķ*D]HWÈ:\ERUF]Èĵ
w w w. o p e r o n . p l
3
Numer
zadania
3RSUDZQDRGSRZLHGěL]DVDG\SU]\]QDZDQLDSXQNWöZ
Liczba
SXQNWöZ
3U]\NïDGSRSUDZQHMRGSRZLHG]L
MnO
4
–
12
–
2+
–
$ MnO
4
ļ
12
3
–
+
O
0Q2
4
–
H
–
$ MnO
4
ļ
12
–
2+
–
$12
3
–
+
O
H
–
0Q2
4
–
12
–
2+
–
$0Q2
4
ļ
12
3
–
+
O
3
SNWļSRSUDZQH]DSLVDQLHGZöFKUöZQDñSRïöZNRZ\FKRUD]SRSUDZQH]DSLVDQLH
]ELODQVRZDQHJRUöZQDQLDUHDNFMLZIRUPLHVNUöFRQHMMRQRZHM
SNWļSRSUDZQH]DSLVDQLHGZöFKUöZQDñSRïöZNRZ\FKRUD]QLHSRSUDZQH]DSL-
VDQLH]ELODQVRZDQHJRUöZQDQLDUHDNFMLZIRUPLHVNUöFRQHMMRQRZHM
SNWļSRSUDZQH]DSLVDQLHMHGQHJR]GZöFKUöZQDñSRïöZNRZ\FKRUD]QLHSR-
SUDZQH]DSLVDQLH]ELODQVRZDQHJRUöZQDQLDUHDNFMLZIRUPLHVNUöFRQHM
jonowej
SNWļQLHSRSUDZQH]DSLVDQLHGZöFKUöZQDñSRïöZNRZ\FKOXEEUDNRGSRZLHG]L
11.
3RSUDZQDRGSRZLHGě
8WOHQLDF]0Q2
4
–
5HGXNWRU12
–
1
1 pkt – poprawne wskazanie utleniacza i reduktora
SNWļQLHSRSUDZQHZVND]DQLHXWOHQLDF]DOXEUHGXNWRUDOXEEUDNRGSRZLHG]L
3RSUDZQDRGSRZLHGě
K
–$J
4e
–
$$J
A
+
O $ O
+
4 e
–
1
SNWļSRSUDZQH]DSLVDQLHGZöFKUöZQDñUHDNFMLHOHNWURGRZ\FK
SNWļSRSUDZQH]DSLVDQLHMHGQHJR]UöZQDñUHDNFMLHOHNWURGRZ\FKEUDNSR-
prawnej odpowiedzi lub brak odpowiedzi
13.
3U]\NïDGSRSUDZQHMRGSRZLHG]L
:ZDUXQNDFKQRUPDOQ\FKZGP
3
O
]QDMGXMÈVLÚJWHJRJD]X6WÈG
ZbFP
3
]QDMGXMHVLÚJ5HDNFMD]DFKRG]ÈFDQDDQRG]LH
+
O $ O
+
4 e
–
=UöZQDQLDUHDNFMLZ\QLNDĝHZUHDNFMLELRUÈXG]LDïPROHHOHNWURQöZVWÈGïDGX-
nek q
NWöU\SU]HSï\QÈïSU]H]HOHNWURGÚMHVWUöZQ\&
2EOLF]HQLHZDUWRĂFLïDGXQNXSRWU]HEQHJRGRRWU]\PDQLDJWOHQX
JWOHQXļ&
JWOHQXļx & x &
2EOLF]HQLHZDUWRĂFLQDWÚĝHQLDSUÈGX
q
I t
I
q
t
C
s
A
3,22 A
=
⋅
⇒
=
=
=
=
965
300
2GSRZLHGě1DWÚĝHQLHSUÈGXSRZLQQRE\ÊUöZQH$
SNWļ]DVWRVRZDQLHSRSUDZQHMPHWRG\REOLF]HñSRSUDZQHZ\NRQDQLHREOLF]Hñ
SRGDQLHSRSUDZQHJRZ\QLNXZUD]]MHGQRVWNÈ
SNWļ]DVWRVRZDQLHSRSUDZQHMPHWRG\REOLF]HñDOHSRSHïQLHQLHEïÚGöZUDFKXQ-
NRZ\FKSURZDG]ÈF\FKGREïÚGQHJRZ\QLNXOXESRGDQLHZ\QLNX]EïÚGQÈ
MHGQRVWNÈOXEEUDNZ\QLNX
SNWļ]DVWRVRZDQLHQLHSRSUDZQHMPHWRG\REOLF]HñOXEEUDNREOLF]Hñ
pobrano z www.sqlmedia.pl
Chemia. Poziom rozszerzony
3UöEQD0DWXUD]23(521(0Lķ*D]HWÈ:\ERUF]Èĵ
w w w. o p e r o n . p l
4
Numer
zadania
3RSUDZQDRGSRZLHGěL]DVDG\SU]\]QDZDQLDSXQNWöZ
Liczba
SXQNWöZ
14.
3U]\NïDGSRSUDZQHMRGSRZLHG]L
6FKHPDWGRĂZLDGF]HQLD
I
II
VWÚĝRQ\NZDVD]RWRZ\9
VWÚĝRQ\NZDVVLDUNRZ\9,
2GF]\QQLNLVWÚĝRQHUR]WZRU\NZDVXD]RWRZHJRVLNZDVXVLDUNRZHJRVI
2EVHUZDFMHSUREöZND]EHQ]HQHPļ]DREVHUZRZDQRĝöïWH]DEDUZLHQLHUR]WZR-
UXLSRMDZLHQLHVLÚ]DSDFKXJRU]NLFKPLJGDïöZSUREöZND]F\NORKHNVDQHPļQLH
zaobserwowano zmian
:QLRVNL:SLHUZV]HMSUREöZFH]QDMGRZDïVLÚEHQ]HQZGUXJLHMF\NORKHNVDQ
3
SNWļSRSUDZQHQDU\VRZDQLHVFKHPDWXGRĂZLDGF]HQLDSRSUDZQH]DSURSRQR-
ZDQLHRGF]\QQLNDLGHQW\ğNDF\MQHJRRUD]SRSUDZQH]DSLVDQLHREVHUZDFML
i wniosków
SNWļSRSUDZQHQDU\VRZDQLHVFKHPDWXGRĂZLDGF]HQLDSRSUDZQH]DSURSRQR-
ZDQLHRGF]\QQLNDLGHQW\ğNDF\MQHJRRUD]SRSUDZQH]DSLVDQLHREVHUZDFML
i niepoprawne zapisanie wniosków
SNWļSRSUDZQHQDU\VRZDQLHVFKHPDWXGRĂZLDGF]HQLDQLHSRSUDZQH]DSUR-
SRQRZDQLHRGF]\QQLNDLGHQW\ğNDF\MQHJRRUD]QLHSRSUDZQH]DSLVDQLH
obserwacji i wniosków
SNWļQLHSRSUDZQHQDU\VRZDQLHVFKHPDWXGRĂZLDGF]HQLDOXEEUDNRGSRZLHG]L
15.
3U]\NïDGSRSUDZQHMRGSRZLHG]L
O
C
O
O
Cl
Ca
2+
–
H
H
Cl
–
3
3 pkt – poprawne narysowanie trzech wzorów
SNWļSRSUDZQHQDU\VRZDQLHGZöFKZ]RUöZ
SNWļSRSUDZQHQDU\VRZDQLHMHGQHJRZ]RUX
SNWļEUDNSRSUDZQHMRGSRZLHG]LOXEEUDNRGSRZLHG]L
pobrano z www.sqlmedia.pl
Chemia. Poziom rozszerzony
3UöEQD0DWXUD]23(521(0Lķ*D]HWÈ:\ERUF]Èĵ
w w w. o p e r o n . p l
5
Numer
zadania
3RSUDZQDRGSRZLHGěL]DVDG\SU]\]QDZDQLDSXQNWöZ
Liczba
SXQNWöZ
16.
3U]\NïDGSRSUDZQHMRGSRZLHG]L
C
n
V
n
C
V
M
m
r
m
r
3
3
HNO
mol
dm
dm
mola
3
=
⇒
=
⋅
=
⋅
=
0 75
0 15
0 1125
,
,
,
g
mol
mola
g
mol
s
s
=
=
⇒
=
⋅
=
⋅
63 01
0 1125
63 01
,
,
,
n
m
M
m
n M
=
=
=
⋅
⇒
⋅
=
⋅
=
g
=
g
%
65 %
p
s
r
r
s
p
7 09
100
100
7 09
100
1
,
%
%
,
C
m
m
m
m
C
0
0 91
7 79
,
,
g
10,91 g
1,40
g
cm
cm
r
r
r
r
r
r
3
3
d
m
V
V
m
d
=
⇒
=
=
=
2GSRZLHGě1DOHĝ\RGPLHU]\ÊFP
3
UR]WZRUXNZDVXD]RWRZHJRV.
SNWļ]DVWRVRZDQLHSRSUDZQHMPHWRG\REOLF]HñSRSUDZQHZ\NRQDQLHREOLF]Hñ
SRGDQLHSRSUDZQHJRZ\QLNXZUD]]MHGQRVWNÈ
SNWļ]DVWRVRZDQLHSRSUDZQHMPHWRG\REOLF]HñDOHSRSHïQLHQLHEïÚGöZUDFKXQ-
NRZ\FKSURZDG]ÈF\FKGREïÚGQHJRZ\QLNXOXESRGDQLHZ\QLNX]EïÚGQÈ
MHGQRVWNÈOXEEUDNZ\QLNX
SNWļ]DVWRVRZDQLHQLHSRSUDZQHMPHWRG\REOLF]HñOXEEUDNREOLF]Hñ
17.
3RSUDZQDRGSRZLHGě
&X
=Q$=Q
&X
1
1 pkt – poprawne zapisanie reakcji
SNWļQLHSRSUDZQH]DSLVDQLHUHDNFMLOXEEUDNRGSRZLHG]L
18.
3RSUDZQDRGSRZLHGě
=Q_=Q
__&X
_&X
1
SNWļSRSUDZQH]DSLVDQLHVFKHPDWXRJQLZD
SNWļQLHSRSUDZQH]DSLVDQLHVFKHPDWXRJQLZDOXEEUDNRGSRZLHG]L
19.
3RSUDZQDRGSRZLHGě
SEM
E
k
E
a
9 9 9
2GSRZLHGě6LïDHOHNWURPRWRU\F]QDRJQLZDZ\QRVL9
1
1 pkt – poprawne obliczenie SEM
SNWļQLHSRSUDZQHREOLF]HQLH6(0OXEEUDNRGSRZLHG]L
3RSUDZQDRGSRZLHGě
=OHZNDQLHELHVNL
=OHZNDF]HUZRQ\
1
SNWļSRSUDZQHSRGDQLHNRORUXXQLZHUVDOQHJRSDSLHUNDZVNDěQLNRZHJR
w dwóch zlewkach
SNWļSRSUDZQHSRGDQLHNRORUXXQLZHUVDOQHJRSDSLHUNDZVNDěQLNRZHJRZMHG-
QHM]OHZFHEUDNSRSUDZQHMRGSRZLHG]LOXEEUDNRGSRZLHG]L
pobrano z www.sqlmedia.pl
Chemia. Poziom rozszerzony
3UöEQD0DWXUD]23(521(0Lķ*D]HWÈ:\ERUF]Èĵ
w w w. o p e r o n . p l
6
Numer
zadania
3RSUDZQDRGSRZLHGěL]DVDG\SU]\]QDZDQLDSXQNWöZ
Liczba
SXQNWöZ
3U]\NïDGSRSUDZQHMRGSRZLHG]L
=OHZND
NH + H O
NH + OH
0,25
mol
dm
0,0
3
2
4
NH
NH
NH
3
3
3
3
→
←
=
⋅
=
⋅
+
−
n
c
V
5
5 dm
0,0125 mola NH
0,0125 mola
0,25 dm
3
3
NH
NH
r
3
3
3
=
=
=
=
c
n
V
0,05
mol
dm
0,05
mol
dm
1,75 10
3
NH
b NH
3
5
3
3
c
K
K
=
⋅
=
>
=
−
2857
400
B
b
b NH
NH
5
NH
3
3
3
1,75 10
0,05
10
10
[OH ]
1,
c
c
=
⋅
=
⋅
=
⋅
=
⋅
=
−
−
−
−
3 5
1 87
4
2
,
,
B
8
87 10
0,05
10
mol
dm
3
⋅
⋅
=
⋅
−
−
2
4
9 35
,
=OHZND
NH
HNO
NH NO
0,25
mol
dm
0,05dm
0,0125 m
3
3
4
3
NH
NH
NH
3
3
3
3
3
+
→
=
⋅
=
⋅
=
n
c
V
o
ola NH
0,25
mol
dm
dm
mola HNO
Po r
3
HNO
HNO
HNO
3
3
3
3
3
3
n
c
V
=
⋅
=
⋅
=
0 2
0 05
,
,
e
eakcji:
0
0,0125
0,0375 mola
0
NH
HNO
HNO
HNO
r
3
3
3
3
n
n
c
n
V
=
=
−
=
=
=
0 05
,
,,0375 mola
0,25 dm
= 0,15
mol
dm
H
0,15
mol
dm
OH
3
3
HNO
3
3
+
=
=
c
−
−
−
+
−
=
=
⋅
10
6
14
H
,67 10
mol
dm
14
3
2GSRZLHGě6WÚĝHQLHMRQöZK\GURNV\ORZ\FK]]OHZFHZ\QRVLĿ
–4
mol/dm
3
.
OXE6WÚĝHQLHMRQöZK\GURNV\ORZ\FK]]OHZFHZ\QRVLĿ
–14
mol/dm
3
.
SNWļSRSUDZQHREOLF]HQLHVWÚĝHQLDMRQöZK\GURNV\ORZ\FKZGZöFKUR]WZRUDFK
SNWļSRSUDZQHREOLF]HQLHVWÚĝHQLDMRQöZK\GURNV\ORZ\FKZMHGQ\PUR]WZRU]H
SNWļEUDNSRSUDZQHMRGSRZLHG]LOXEEUDNRGSRZLHG]L
3U]\NïDGSRSUDZQHMRGSRZLHG]L
S
I
S
I
0 PbSO
r
3
0 PbCrO
r
mol
dm
mol
4
4
1 05 10
1 34 10
4
7
=
=
⋅
=
=
⋅
−
−
,
,
d
dm
3
2GSRZLHGě6LDUF]DQVIRïRZLXIIPDZ\ĝV]ÈUR]SXV]F]DOQRĂÊMHVW]DWHPOHSLHM
UR]SXV]F]DOQ\0RĝOLZHMHVWSU]HSURZDG]HQLHVROLWUXGQRUR]SXV]F]DOQ\FKZWUXG-
QLHMUR]SXV]F]DOQH]DWHPSU]HGVWDZLRQDUHDNFMD]DMG]LHZSUDZR
1
SNWļ]DVWRVRZDQLHSRSUDZQHMPHWRG\REOLF]HñSRSUDZQHZ\NRQDQLHREOLF]Hñ
podanie poprawnej odpowiedzi
SNWļ]DVWRVRZDQLHQLHSRSUDZQHMPHWRG\REOLF]HñOXEEUDNREOLF]Hñ
pobrano z www.sqlmedia.pl
Chemia. Poziom rozszerzony
3UöEQD0DWXUD]23(521(0Lķ*D]HWÈ:\ERUF]Èĵ
w w w. o p e r o n . p l
7
Numer
zadania
3RSUDZQDRGSRZLHGěL]DVDG\SU]\]QDZDQLDSXQNWöZ
Liczba
SXQNWöZ
3RSUDZQDRGSRZLHGě
,+
S
+
O m+6
–
+
3
O
,,+6
–
+
O m S
ļ
+
3
O
1
1 pkt – poprawne podanie dwóch reakcji dysocjacji
SNWļSRSUDZQHSRGDQLHMHGQHMUHDNFMLG\VRFMDFMLEUDNSRSUDZQHMRGSRZLHG]LOXE
brak odpowiedzi
3RSUDZQDRGSRZLHGě
K
K
a
3
a
3
[HS ] [H O ]
[H S]
[S ] [H O ]
[HS ]
1
2
2
2
=
⋅
=
⋅
−
+
−
+
−
1
SNWļSRSUDZQHSRGDQLHGZöFKZ\UDĝHñQDVWDïHG\VRFMDFML
SNWļSRSUDZQHSRGDQLHMHGQHJRZ\UDĝHQLDQDVWDïÈG\VRFMDFMLEUDNSRSUDZQHM
odpowiedzi lub brak odpowiedzi
3RSUDZQDRGSRZLHGě
>+
3
O
@>+6
–
@>6
ļ
@
1
SNWļSRSUDZQHXV]HUHJRZDQLH
SNWļQLHSRSUDZQHXV]HUHJRZDQLHOXEEUDNRGSRZLHG]L
3RSUDZQDRGSRZLHGě
a
w prawo
b
w lewo
c
w lewo
d
QLHZSï\QLH
SNWļSRSUDZQDRGSRZLHGěZF]WHUHFKSRGSXQNWDFK
SNWļSRSUDZQDRGSRZLHGěZWU]HFKSRGSXQNWDFK
SNWļSRSUDZQDRGSRZLHGěZGZöFKOXEMHGQ\PSRGSXQNFLHEUDNSRSUDZQHM
odpowiedzi lub brak odpowiedzi
3U]\NïDGSRSUDZQHMRGSRZLHG]L
pV
nRT
n
pV
RT
Pa
m
8,314
J
mol K
3
=
⇒
=
=
⋅
⋅
⋅
⋅
⋅
−
1 013 10
5 10
29
5
3
,
3
3 K
= 0,21mola
J&D12
3
ļPROH12
x
ļPROD12
&
x
J&D12
3
2GSRZLHGě1DOHĝ\RGZDĝ\ÊJD]RWDQXV wapnia.
SNWļ]DVWRVRZDQLHSRSUDZQHMPHWRG\REOLF]HñZ\NRQDQLHSRSUDZQ\FKREOL-
F]HñLSRGDQLHSRSUDZQHJRZ\QLNXZUD]]MHGQRVWNÈ
SNWļ]DVWRVRZDQLHSRSUDZQHMPHWRG\REOLF]HñSRSUDZQHZ\NRQDQLHREOLF]Hñ
SRGDQLHSRSUDZQHJRZ\QLNX]EïÚGQÈMHGQRVWNÈOXEEH]MHGQRVWNL
SNWļ]DVWRVRZDQLHQLHSRSUDZQHMPHWRG\REOLF]HñOXEEUDNREOLF]Hñ
3U]\NïDGSRSUDZQHMRGSRZLHG]L
&+
3
_
&+
3
Ľ&Ľ&+
Ľ&+Ľ&+
Ľ&+
3
_
_
&+
3
&+
3
1D]ZDV\VWHPDW\F]QDļWULPHW\ORKHNVDQ
1
SNWļSRSUDZQHQDU\VRZDQLH]ZLÈ]NXRUD]SRSUDZQHSRGDQLHQD]Z\V\VWHPD-
tycznej
SNWļSRSUDZQHQDU\VRZDQLH]ZLÈ]NXDOHQLHSRSUDZQHSRGDQLHQD]Z\V\VWHPD-
W\F]QHMQLHSRSUDZQHQDU\VRZDQLH]ZLÈ]NXOXEEUDNRGSRZLHG]L
pobrano z www.sqlmedia.pl
Chemia. Poziom rozszerzony
3UöEQD0DWXUD]23(521(0Lķ*D]HWÈ:\ERUF]Èĵ
w w w. o p e r o n . p l
8
Numer
zadania
3RSUDZQDRGSRZLHGěL]DVDG\SU]\]QDZDQLDSXQNWöZ
Liczba
SXQNWöZ
C H
4 O
3 CO
2 H O
C H
3 C
2
3
4(g)
2(g)
2(g)
2
(g)
3
4(g)
(s)
+
→
+
→
+
H
H
3 CO
3
2
O
3 CO
3
3 C
3
2
O
2(g)
1
0
(g)
2(g)
2(g)
3
0
(s)
2(g)
−
+
→
⋅
+
%
%
H
H
→
⋅
→
⋅
+
→
3 CO
3
2 H O
2 H O
2
2 H
O
2 H
(g)
2
0
2
(c)
2
(g)
5
0
2(g)
2(g)
2
%
%
H
H
O
O
2
(c)
4
0
0
1
0
3
0
2
0
5
0
4
0
⋅
=
−
+
⋅
+
⋅
+
⋅
+
⋅
%
%
%
%
%
%
%
H
H
H
H
H
H
H
3
3
2
2
kJ
mol
=
−
1945 8
,
2GSRZLHGě(QWDOSLDUHDNFMLFDïNRZLWHJRVSDODQLDSURS\QXZ\QRVLļN-PRO
SNWļ]DVWRVRZDQLHSRSUDZQHMPHWRG\REOLF]HñZ\NRQDQLHSRSUDZQ\FKREOL-
F]HñLSRGDQLHSRSUDZQHJRZ\QLNXZUD]]MHGQRVWNÈ
SNWļ]DVWRVRZDQLHSRSUDZQHMPHWRG\REOLF]HñDOHSRSHïQLHQLHEïÚGöZUDFKXQ-
NRZ\FKSRGDQLHEïÚGQHJRZ\QLNXOXEEUDNZ\QLNX
SNWļ]DVWRVRZDQLHQLHSRSUDZQHMPHWRG\REOLF]HñEïÚGQHZ\NRQDQLHREOLF]Hñ
OXEEUDNREOLF]Hñ
3RSUDZQDRGSRZLHGě
:HZQÈWU]PLFHOL]QDMGXMHVLÚF]ÈVWNDSRODUQD
:HZQÈWU]PLFHOL]QDMGXMHVLÚF]ÈVWNDQLHSRODUQD
1
SNWļSRSUDZQHX]XSHïQLHQLHGZöFK]GDñ
SNWļSRSUDZQHX]XSHïQLHQLHMHGQHJR]GDQLDEUDNSRSUDZQHMRGSRZLHG]LOXE
brak odpowiedzi
31.
3U]\NïDGSRSUDZQHMRGSRZLHG]L
0OHNR]DEDUZLDVLÚQDNRORUĝöïW\
1
1 pkt – poprawne podanie obserwacji
SNWļQLHSRSUDZQDRGSRZLHGěOXEEUDNRGSRZLHG]L
pobrano z www.sqlmedia.pl
Chemia. Poziom rozszerzony
3UöEQD0DWXUD]23(521(0Lķ*D]HWÈ:\ERUF]Èĵ
w w w. o p e r o n . p l
9
Numer
zadania
3RSUDZQDRGSRZLHGěL]DVDG\SU]\]QDZDQLDSXQNWöZ
Liczba
SXQNWöZ
3U]\NïDGSRSUDZQHMRGSRZLHG]L
'RĂZLDGF]HQLH
Cu(OH)
2(s)
aldehyd cynamonowy
2EVHUZDFMHZ\WUÈFLïVLÚFHJODVWRF]HUZRQ\RVDG
5öZQDQLHUHDNFML
+ 2 Cu(OH)
2
+ Cu
2
O + 2 H
2
O
HC
CH
H
C
O
HC
CH
OH
C
O
T
3
SNWļSRSUDZQHQDU\VRZDQLHVFKHPDWXGRĂZLDGF]HQLDSRSUDZQH]DSLVDQLH
obserwacji oraz poprawne zapisanie równania reakcji chemicznej
SNWļSRSUDZQHQDU\VRZDQLHVFKHPDWXGRĂZLDGF]HQLDSRSUDZQH]DSLVDQLH
obserwacji oraz niepoprawne zapisanie równania reakcji chemicznej
SNWļSRSUDZQHQDU\VRZDQLHVFKHPDWXGRĂZLDGF]HQLDQLHSRSUDZQH]DSLVDQLH
obserwacji oraz niepoprawne zapisanie równania reakcji chemicznej
SNWļQLHSRSUDZQHQDU\VRZDQLHVFKHPDWXGRĂZLDGF]HQLDOXEEUDNRGSRZLHG]L
33.
3U]\NïDGSRSUDZQHMRGSRZLHG]L
'RĂZLDGF]HQLH
H
2
2RUDQĝPHW\ORZ\
CO
2
2EVHUZDFMHUR]WZöU]DEDUZLïVLÚQDF]HUZRQR
:QLRVNLZRGDQDV\FRQDWOHQNLHPZÚJODIV wykazuje odczyn kwasowy
3
SNWļSRSUDZQHQDU\VRZDQLHVFKHPDWXGRĂZLDGF]HQLDSRSUDZQH]DSLVDQLH
obserwacji oraz poprawne zapisanie wniosków
SNWļSRSUDZQHQDU\VRZDQLHVFKHPDWXGRĂZLDGF]HQLDSRSUDZQH]DSLVDQLH
obserwacji oraz niepoprawne zapisanie wniosków
SNWļSRSUDZQHQDU\VRZDQLHVFKHPDWXGRĂZLDGF]HQLDQLHSRSUDZQH]DSLVDQLH
obserwacji oraz niepoprawne zapisanie wniosków
SNWļQLHSRSUDZQHQDU\VRZDQLHVFKHPDWXGRĂZLDGF]HQLDOXEEUDNRGSRZLHG]L
pobrano z www.sqlmedia.pl
Chemia. Poziom rozszerzony
3UöEQD0DWXUD]23(521(0Lķ*D]HWÈ:\ERUF]Èĵ
w w w. o p e r o n . p l
10
Numer
zadania
3RSUDZQDRGSRZLHGěL]DVDG\SU]\]QDZDQLDSXQNWöZ
Liczba
SXQNWöZ
34.
3RSUDZQDRGSRZLHGě
Ř
O
O
C
CH
CH
3
NH
2
1
1 pkt – poprawne narysowanie wzoru
SNWļQLHSRSUDZQHQDU\VRZDQLHZ]RUXOXEEUDNRGSRZLHG]L
35.
3RSUDZQDRGSRZLHGě
a
2+
2Ľ&2Ľ&+
3
_
_
&+
3
Ľ&+Ľ&22+&+
3
&22+
H SO
2
4
→
←
&+
3
Ľ&+Ľ&22++
O
b
2+
2+
_
_
&+
3
Ľ&+Ľ&22+&+
3
2+
H SO
2
4
→
←
&+
3
Ľ&+Ľ&22&+
3
+
O
c
2+
2+
_
_
&+
3
Ľ&+Ľ&22+1D2+ →
&+
3
Ľ&+Ľ&221D+
O
3
SNWļSRSUDZQH]DSLVDQLHUöZQDñUHDNFMLZWU]HFKSU]\SDGNDFK
SNWļSRSUDZQH]DSLVDQLHUöZQDñUHDNFMLZGZöFKSU]\SDGNDFK
SNWļSRSUDZQH]DSLVDQLHUöZQDñUHDNFMLZMHGQ\PSU]\SDGNX
SNWļQLHSRSUDZQH]DSLVDQLHUöZQDñUHDNFMLWU]HFKSU]\SDGNDFKOXEEUDNRGSR-
wiedzi
36.
3RSUDZQDRGSRZLHGě
:]öUDOGHK\GX
&+
3
_
&+
3
Ľ&+Ľ&+2
5HDNFMD
&+
3
&+
3
_
_
&+
3
Ľ&+Ľ&+2+
Pt
→
&+
3
Ľ&+Ľ&+
2+
5HDNFMD
&+
3
&+
3
_
_
&+
3
Ľ&+Ľ&+
2+
Al O
2
3
→
&+
3
Ľ&=&+
+
O
3
SNWļSRSUDZQHSRGDQLHZ]RUX]ZLÈ]NXRUD]SRSUDZQH]DSLVDQLHGZöFKUöZQDñ
reakcji
SNWļSRSUDZQHSRGDQLHZ]RUX]ZLÈ]NXRUD]SRSUDZQH]DSLVDQLHMHGQHJRUöZ-
nania reakcji
SNWļSRSUDZQHSRGDQLHZ]RUX]ZLÈ]NXRUD]QLHSRSUDZQH]DSLVDQLHUöZQDñ
reakcji w dwóch przypadkach
SNWļQLHSRSUDZQHSRGDQLHZ]RUX]ZLÈ]NXOXEEUDNRGSRZLHG]L
pobrano z www.sqlmedia.pl