Hydrol L-HMHLP 15_MSDS_2008

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MATERIAL SAFETY DATA SHEET

according to the instruction of the Minister of Health of 13 November 2007, (Dz. U. (official journal) No. 215

item 1588)

Material Safety Data Sheet update date: 29.10.2008
Previous version preparation date: 17.03.2004

1. SUBSTANCE/ PRODUCT AND COMPANY IDENTIFICATION

1.1. Trade name: Hydraulic oil Hydrol L-HM/HLP 15
1.2. Substance/ product application: it is intended to use in highly loaded systems of transfer of power and drive

and hydraulic control of equipment, working in conditions of elevated
temperature and high humidity.

1.3.  Company identification:

Company name:    Orlen Oil Sp. z o. o.
Address:                 ul. Armii Krajowej 19, 30-150 Kraków
Phone number :     + 48 (012) 665 55 00

, emergency phone number +48 (013) 438 45 24 working hrs: 7 a.m – 3 p.m.

Fax number: +48 (012) 665 55 01, +48 (013) 438 43 21
e-mail:

msds@orlenoil.pl

2. HAZARD IDENTIFICATION

Hazard classification: The product is not classified as hazardous.

Fire hazard:

The product does not pose any particular fire or explosion hazard.

Toxicological hazard:

The product does not contain hazardous components that would pose
immediate threat to human health.

Toxic hazard for the
environment:

The product is of little harmful effect to aquatic and terrestrial organisms;
but please note that environment pollution by oil is prohibited by law.

Oil

may be hazardous for the environment and living organisms in the event of
misuse or spill due to its limited biodegradability.

3. COMPOSITION AND INFORMATION ON INGREDIENTS

Generic chemical name

% wt

CAS No

EC (WE) No

Warning

symbols

(labels)

Risk Phrase(s):

Lubricant oils (crude oil), hydrotreated
hydrocarbons C

-C

, inert base oil.

Unspecified base oil.

< 70

72623-87-1

276-738-4

H Note

L Note

None

Zinc-Alkyl Dithiophosphate

≤

0,29

68649-42-3

272-028-3

R41, R51/53

Bound alkylphenols

≤

0,17

R36/38,

R51/53

Distillates (petroleum), chemically
neutralized light. Unspecified
petroleum fraction.

< 35

64742-31-0

265-132-5

R65, R66

4. FIRST AID MEASURES

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Respiratory
system:

At ambient temperatures, the oil does not display harmful impact on the respiratory system
thanks to the low content of non-volatile components. The risk of inhalation exists only in
the case of the product forming a mist or being heated. Provide access of fresh air. If no
recovery is observed, ensure medical assistance.

Skin:

Wash with plenty water with soap. Should an irritation develop, ensure medical assistance.
If the skin is exposed to contact with high pressure mist, the product may penetrate into the
organism. Should this occur, contact a physician even if no negative symptoms are
observed.

Eyes:

Rinse open eyes with water for 15 minutes. Should an irritation develop, ensure medical
assistance.

Ingestion:

Due to organoleptic properties of the product, little probability of ingestion occurs. Do not
induce vomiting. Do not administer anything orally. If no recovery is observed, ensure
medical assistance.

5. FIRE FIGHTING MEASURES

Recommended
extinguishing media:

Foam, water mist, dry extinguishing chemical powders, CO

, sand or soil only in the

event of small fires.

Protective means:

Complete protective clothing with individual self-contained breathing apparatus.

Unsuitable
extinguishing media:

Do not use condensed streams of water onto the burning liquid surface. It results in
scattering the fire centres. Sprayed water or water mist may be applied for cooling.

Fire fighting hazards:

Vapours are generated in high temperatures which, when mixed with air and contact
with a source of ignition may burn in the open space or explode in a contained room.
Product vapours are heavier than air and may spread over long distances close to the
ground level and, meeting a source of ignition (flame), they may cause ignition again.
Highly dispersed product mist may ignite below the standardized flashpoint. Burning
fluid may float on water surface.

Combustion products:

Carbon oxides, nitrogen oxides, sulphur oxides and other health-hazardous gases.

6. ACCIDENTAL RELEASE MEASURES

Personal (individual)
protection measures:

Avoid contact with skin and eyes, use coated clothing and rubber-soled shoes.

Environmental protection
(precautions) – large spills:

Contain large spills with sand, soil or absorbing material barriers. Collect the
released material using equipment available and place it into a sealed, properly
labelled container for further recovery or storage in a suitable place. The residue
treat as a small spill.

Environmental protection
(precautions) – small spills:

Collect the released residue having mixed the spill with soil, sand or another
absorbent, using available equipment, and place it into a sealed, properly
labelled container to be stored in a suitable place.

7. HANDLING AND STORAGE

HANDLING PROCEDURES:
User protection:

Use adequate ventilation in the cases of conditions resulting in vapour or mist
generation. Apply all measures to limit the risk of contact, especially with used oil.
Keep away from inflammable materials, food and drinks.
During handling and storage, follow the general work safety and hygiene as well as
fire rules and regulations, the use of protective chemical goggles and suitable
protecting clothing is recommended.

Explosion or fire
protection (precautions):

Empty containers and tanks may contain inflammable or explosive vapours.
Welding, heating, cutting or drilling of tanks or containers with oil or its residue,
after emptying, is prohibited. The residue of oil left behind in containers, as a result
of high temperature, may generate explosive vapour mixture (oil mist) which may
cause explosion.
Clothing, paper and rags (cloth, lint) used to remove spilled oil, soaked with the oil,
pose a fire hazard – avoid accumulating such materials. Get them disposed of
immediately after use following adequate precautions.

Precautions:

Reduce fire hazard using machines and equipment in an appropriate way:

Hydraulic oil Hydrol L-HM/HLP 15

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to avoid spilling or splashing the oil over heated or live machinery parts.

to prevent oil mist generation especially in pressure systems, remembering that
fire hazard increases when mist concentration reaches the level of approx. 45
g/m

to avoid prolonged or repeated contact of skin with the oil or oil-soaked clothes.

In the event of skin contact immediately wash the affected (soiled) place with
plenty of water and soap.

Do not use abrasive (scouring) agents or kerosene solvents for body washing
purposes.

Immediately change the contaminated working clothing.

Do not inhale vapour and/or mist.

Avoid contact of the substance with strong oxidants.

When handling the product, do not eat, drink or smoke.

Use only hydrocarbon-resistant containers, connections and equipment.

STORAGE

Conditions:

Store in room temperature, protect from contact with water or moisture, keep away
from sources of ignition.
Keep containers legibly labelled and sealed.
Make efforts to prevent the release of the product to the ground and water.

Contraindications:

Avoid contact with oxidants.
Store away from heating devices.

Packaging:

Use hydrocarbon-resistant packaging (containers). Use of original manufacturer’s
containers is recommended.

SPECIFIC APPLICATIONS: -

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Use well-ventilated rooms, if there is a risk of oil mist generation, use closed
circulation systems and good ventilation.

Skin protection:

Requires no special protection, though to minimise the potential risk, the use of
protective clothing and oil resistant protective gloves is recommended.

Eyes protection:

Requires no special protection, though the use of protective chemical goggles is
a good practice.

Respiratory system
protection:

In normal conditions it does not require special protection.
If there is a risk of exceeding the permissible concentration limits or of oil mist
generation, protective masks should be used.

Exposure control parameters
(according to instruction of MPiPS Dz.U (official journal) No 217, item 1833, 2002 with later amendments.)

Mineral oils ( liquid phase aerosol ):
NDS: 5 mg/ m

, NDSCh: 10 mg/ m

, NDSP: not defined

DNEL: no data
PNEC : no data
Kerosine:
NDS: 100 mg/ m

, NDSCh: 300 mg/ m

, NDSP: not defined – for light products

Recommended methods of exposure assessment in the air:
- PN-Z-04008-7:2002 – “Air purity protection -- Sampling methods -- Principles of air sampling in work place
and interpretation of results”
- PN-Z-04108-6:2006 „Air purity protection -- Determination of mineral oil (liquid phase aerosol) in work places
by absorption spectrometry method in ultra-violet ”.
-PN-Z-04108-5:2006 „Air purity protection -- Tests for content of oils -- Determination of mineral oil (liquid
phase of aerosol) in work places by absorption spectrometry method in infra-red”

Means ensuring the proper hygiene:
General rules of hygiene should be followed: do not eat, do not drink, do not smoke during handling the product.
Contaminated clothing should be immediately removed and changed. The product can be easily adsorbed

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through the skin. Not allowing to be doused with the product, especially when it comes to large body areas.
Always wash hands with water and soap after finishing work.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state (appearance)/ colour/
odour:

Clear liquid / amber to light brown / oil-specific odour.

No data

Boiling point:

Over 300°C

Flash point:

Over 175°C

Pour point:

Below -30 °C

Oxidizing properties:

No data

Vapour pressure:

No data. Negligible in normal use conditions.

Solubility in water and solvents:

Insoluble in water. Soluble in hydrocarbon solvents.

Distribution ratio n-octanol/water

No data

Density:

Approx. 870 kg/m

Kinematic viscosity at 40°C

Approx. 14 mm

Explosion limits:

Oil mist flammability at concentration of approx. 45 g/m

Autoignition point:

No data. Negligible in normal use conditions

Evaporation rate:

No data

Corrosive properties:

Does not show corrosive properties.

10. STABILITY AND REACTIVITY

Stability:

The product is stable in normal storage, handling and use conditions.

Incompatible (hazardous)
materials (to avoid):

Avoid contact with strong oxidants.

Hazardous conditions (to avoid):

Heat (temperature above flash point), sources of flame and sparks, static
electricity.

Hazardous decomposition
products:

Incomplete combustion may result in emissions of gaseous CO, CO

soot.

11. TOXICOLOGICAL INFORMATION

ROUTES OF EXPOSURE
(ENTRY):

Eye contact effects:

Neutral or may cause slight irritation of eyes.

Skin contact effects:

Neutral or may result in slight skin irritation, redness or drying.
Prolonged contact of the product with skin and not following the general
work safety and hygiene rules may cause dermatologic problems.
Dangerous case may occur when the oil under pressure penetrates skin
and gets to subcutaneous tissues..

Respiratory system contact effects:
Inhalation :

At ambient temperatures, the oils are neutral thanks to the low volatility.
Inhaled mists or vapours at high temperatures (over 60

C) may cause

respiratory system irritation.

Suction and ingestion

Little probability of direct exposure by suction occurs. Incidental
exposure may occur during vomiting. Higher doses may cause severe
pneumonological problems.

Doses and concentrations toxic to
animals:

No data

12. ECOLOGICAL INFORMATION

Mobility (spreading):

- in soil

In normal conditions of use the product does not cause any hazard for
soil and the environment.
May be hazardous for the environment and living organisms (especially

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aquatic) in the event of misuse or in emergency situations, e.g. spills,
when the product penetrates into the ground, causing contamination of
ground waters.

- in water

The product is insoluble in water, spreads over water surfaces forming a
thin oil film.

Ecotoxicity:

No data

Degradability:

No data

Bioaccumulation:

No data

13. DISPOSAL CONSIDERATIONS

Should a need to dispose of waste and/or product that has lost its useful properties (product spilt or mixed with
absorbers) occur, such substance needs to be provided to the authorized entity possessing the official permission
for collection of such type of waste. It is not allowed to dispose the product together with household waste.
Make efforts to prevent the release of the product to the sewage system.

Waste classification (according to the Order of the Minister of the Environment, Dz. U. (official journal), No
112, item 1206)
Waste code : 13 01 10 -

Mineral-based non-chlorinated hydraulic oils.

14. TRANSPORT INFORMATION

INTERNATIONAL REGULATIONS

Transport by land RID/ADR:

Not applicable

Transport by sea IMDG:

Not applicable

Transport by air:

Not applicable

Additional information:

Does not pose a hazard during transport and does not require
special treatment (handling) procedure.

15. REGULATORY INFORMATION

Applicable domestic (national) regulations:

1. Regulation of the Minister of Health of 28

September, 2005, regarding the List of Hazardous

Substances with their classification and labelling (marking) – (Dz. U. (official journal) No 201, item
1674)

2. Regulation of the Minister of Health of 13

November, 2007, regarding the Material Safety Data Sheet

(Dz. U. (official journal) No 215, item 1588)

3. Regulation of the Minister of Health of 14

August, 2002, regarding the duty of providing the Material

Safety Data Sheet for some preparations not classified as hazardous (Dz. U. (official journal) No 142,
item 1194). AMENDMENT - Order of the Minister of Health of 30

August, 2007, repealing the

regulation regarding the duty of providing the Material Safety Data Sheet for some preparations not
classified as hazardous (Dz. U. (official journal) No 161/2007, item 1144).

4. Regulation of the Minister of Health of 2

September, 2003, regarding the criteria and methods of

classification of chemical substances and preparations (Dz. U. (official journal) No 171, item 1666)
AMENDMENT - Order of the Minister of Health of 4

September, 2007, (Dz. U. (official journal) No

174/2007, item 1222)

5. Regulation of the Minister of Health of 2

September, 2003, regarding the labelling of packaging of

hazardous substances and preparations (Dz. U. (official journal) No 173, item 1679) with later
amendments

6. Regulation of the Minister of Health of 30

April 2004 regarding the hazardous substances and

preparations the packaging of which must be fitted with child resistant fastening and tactile warning of
danger (Dz.U. (official journal) No 128 item 1348)

7. Regulation of the Minister of Economics, Labour and Social Policy of 17

April 2003 regarding the

restrictions, prohibitions and terms of the placing on the market or use of dangerous substances and
preparations

(Dz.U. (official journal) No 86/2003, item799)

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8. Regulation of the Minister of Health of 18

February 2003 regarding the method of assessment of risk

to man and the environment caused by chemical substances (Dz.U. (official journal) No 52/2003, item
467)

9. Regulation of the Minister of Health of 18

February 2003 regarding the detailed data required for

notification of new chemical substance documentation, what is essential for the

assessment of risk to

man and the environment caused by this chemical substance,

(Dz.U. (official journal) No 50/2003,

poz.437) AMENDMENT – Regulation of the Minister of Health of 22

August 2007 (Dz. U. (official

journal) No 160/2007 item 140)

10. Regulation of the Minister of Health of 4

October 2001 regarding the giving

the Statute of the

Inspector for Chemical Substances and Preparations (Dz.U. (official journal) No 121, item 1308)

11. Regulation of the Minister of Health of 18

February 2003 regarding the detailed data which should be

provided to the Inspector for Chemical Substances and Preparations by the manufacturer or importer in
case of placing on the market in Poland some of new chemical substances (Dz.U. (official journal) No
50/2003, item 436)

12. Regulation of the Minister of Health of 14

March 2003 regarding the methods of marking of places,

pipelines, containers and tanks in which hazardous substances and preparations are stored (Dz.U.
(official journal) No 61/2003, item 552)

13. Regulation of the Minister of Health of 17

January 2003 regarding the information about hazardous

preparations for which providing Material Safety Data Sheet is not required (Dz.U. (official journal) No
19 of 07.02.2003, item 170)

14. Regulation of the Minister of Health of 18

February 2003 regarding the determination of quantity

thresholds for new substances turnover and type of testing required in case of these thresholds
exceeding (Dz.U. (official journal) No 50, item 438)

15. Regulation of the Minister of Health of 30

April 2003 regarding the amounts and methods of payment

of fees on notification of new chemical substances and providing additional test results (Dz.U. (official
journal) No 116, item 1102)

16. Regulation of the Minister of Health of 4

June 2003 regarding the criteria which must be fulfilled by

laboratories and other units conducting tests on chemical substances and preparations and on the control
and verification of the fulfillment of these criteria

( Dz.U. (official journal) No 116, item 1103 )

17. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006

concerning the Registration, Evaluation, Authorization and Restriction of Chemicals (REACH)
establishing a European Chemicals Agency, amending Directive 1999/45/EC

Labelling and classification (information placed on the label): The safe product and does not require special

labelling on unit packages.

16. OTHER INFORMATION

Labelling  as per section 3.

L  Note:    mineral  base  oils  applied  are  not  classified  as  carcinogenic;  they  contain  less  than  3%  of  the  DMSO
extract, as per the measurement by the method specified in IP 346

Xn - harmful
X

– irritant

N – Hazardous to environment
R36/38 - Irritating to eyes and skin
R41 – Risk of serious damage to eyes
R 51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R 65 – Harmful: may cause lung damage if swallowed
R 66 – Repeated exposure may cause skin dryness or cracking