dP
dT

=

H

T V

∆

∆

       

d ln P

dT

=

H

RT

p(s)

2

∆

 

ln

P

P

H

R

1

T

1

T

2

1

p,(s)

2

1

= −

−











∆

 

ln P

H
RT

+ const

p,(s)

= −

∆

 

 

P

P x

A

A

0

A

=

⋅

    

P

P x

B

B

0

B

=

⋅

    

x

x

1

A

B

+

=

 

y

P

P

A

A

=

           

y

P

P

B

B

=

           

y

y

1

A

B

+

=

 

P = P

P = P x

P x

A

B

A

0

A

B

0

B

+

⋅

+

⋅

 

X (n + n ) = n

n

= n x

n y

A

c

p

A,c

A,p

c

A

p

A

+

⋅

+

⋅

 

W (m + m ) = m

m

= m w

n z

A

c

p

A,c

A,p

c

A

p

A

+

⋅

+

⋅

n
n

=

X - x

y - X

p

c

A

A

A

A

        

m
m

=

W - w

z - W

p

c

A

A

A

A

 

 

P P x

A

0

A

=

⋅

       

∆P
P

=

P - P

P

= x

A

0

A

0

A

0

B

 

 

lnx

H

R

1

T

1

T

A

p

w

w,A

= −

−











∆

 

∆T = T - T

= K m

w

w

w,A

e

⋅

 

K =

RT

M

H 1000

e

w,A

2

A

p

⋅

⋅

∆

 

dP
dT

=

H

T V

∆

∆

       

d ln P

dT

=

H

RT

p(s)

2

∆

 

ln

P

P

H

R

1

T

1

T

2

1

p,(s)

2

1

= −

−











∆

 

ln P

H
RT

+ const

p,(s)

= −

∆

 

 

P

P x

A

A

0

A

=

⋅

    

P

P x

B

B

0

B

=

⋅

    

x

x

1

A

B

+

=

 

y

P

P

A

A

=

           

y

P

P

B

B

=

           

y

y

1

A

B

+

=

 

P = P

P = P x

P x

A

B

A

0

A

B

0

B

+

⋅

+

⋅

 

X (n + n ) = n

n

= n x

n y

A

c

p

A,c

A,p

c

A

p

A

+

⋅

+

⋅

 

W (m + m ) = m

m

= m w

n z

A

c

p

A,c

A,p

c

A

p

A

+

⋅

+

⋅

n
n

=

X - x

y - X

p

c

A

A

A

A

        

m
m

=

W - w

z - W

p

c

A

A

A

A

 

 

P P x

A

0

A

=

⋅

       

∆P
P

=

P - P

P

= x

A

0

A

0

A

0

B

 

 

lnx

H

R

1

T

1

T

A

p

w

w,A

= −

−











∆

 

∆T = T - T

= K m

w

w

w,A

e

⋅

 

K =

RT

M

H 1000

e

w,A

2

A

p

⋅

⋅

∆